Tuesday, May 31, 2011

Alkenes and Alkanes

Today we learned about alkenes and alkynes.






They are different from alkanes because they can form double(alkene) and triple(alkyne) bonds.

Alkenes are formed with double bonds between carbon atoms and the ending is -ene.

Example.


Let us name this.
If this was an alkane, it would end in -ane and its name would be 2-methylpentane.
However it is an alkene as evidenced by the double bond.

Therefore the name is 4-methyl
Then you write the number of the carbon# the double bond comes after so 2-pent-ene

so the name of this compound is 4-methyl-2-pentene.

Alkynes are exactly the same as alkenes except when you name it, change the ending to -yne. They use triple bonds.






Name this.

First count the parent hydrocarbon.
=4 so Butane.
Then you take into account the triple bond so the name changes to butyne.

Since there are no branched hydrocarbons, nothing needs to be added except the position of the triple bond.
This is added in front of  the word butyne

It is 2-butyne.

http://www.youtube.com/watch?v=7XbYhjyUI-M


Sunday, May 29, 2011

Organic Chemistry



Organic Chemistry is the study of compounds containing carbon. These compounds can be formed in several ways, and may appear in a straight line, circular or branched pattern. They also have low melting points. To combine with other atoms they can form single,double or triple bonds.



 A hydrocarbon is a compound containing only carbon and hydrogen.
Alkane: A saturated hydrocarbon involving only single bonds.

Here are some examples of alkanes:

The chemical formula for alkanes is CNH2N+2

Methane: CH4
Ethane: C2H6
Propane : C3H8
Butane: C4H10

* An alkyl group is an alkane that loses an atom of hydrogen.
A branched hydrocarbon is a hydrocarbon attached to the original carbon atom.

Thursday, May 19, 2011

Chemical Bonding

Chemical bonding is molecules and atoms being attracted to each other and this allows them to combine to form chemical compounds.

There are 3 types of bonding:

Ionic Bonding: Is the transfer of atoms to form positive or negative ions.
Non-Polar Covalent Bonding- Is the unequal sharing of electrons
Polar Covalent Bonding : sharing of electrons equally.

IONIC:

Ionic bonding involves metal and non-metals. The force that powers ionic bonding is called the electrostatic force, which is the attraction or repulsion of charged particles. Electronegativity is also an important concept behind this bonding. Metal electronegativity is low and non metal electronegativity is high. As result, a high ionization energy is created. To determine how electrons are shared, electronegativity difference must be found.

ENeg Diff= ENeg 1 - ENeg 2
ENeg Diff  less than 0.5 it is a non polar
ENeg Diff greater than 0.5 and less than 1.8 is is polar covalent bond
 ENeg Diff greater than 1.8 is it ionic

Polarity: is the electrical balance or imbalance of the molecule. If the molecule is electrically unbalanced, then it is polar. This is caused by electronegativity. If the EN is high, the shared electrons will be pulled more to the atom. A partial negative results from high electronegativity and a partial positive results from a  low one.


In a Non- polar bond, it is one of the simplest, only involving the sharing of electrons to create full valence shells. Intramolecular forces in the molecule hold the atoms of the molecule together.
However, intermolecular forces act between molecules and are responsible for bonding.

A London force is a weak intermolecular force. They occur because of temporary dipolar attractions. A dipole is when one side is slightly positive and the other side is slightly negative ,creating partial separation.



Tuesday, May 10, 2011

Drawing Electron Dot Diagrams and Lewis Dot Diagrams



Let us examine an example of an electron dot or Lewis diagram.

1. The centre of the diagram, the atomic symbol represents the nucleus.
2. Each dot represents an electron in an electron dot diagram. These are only the valence electrons, or the electrons in the outermost shell.
3. In a Lewis diagram, lines represent a  bond between two electrons.
Here is an example. Because Nitrogen has 5 valence electrons and hydrogen has 1. Hydrogen needs 1 electron to become full and nitrogen needs 3.
Therefore, in NH3, N and H share electrons so that H is full with 2. and N, being surrounded on 3 sides gets 3 electrons.


In a structural diagram, electron bonds can be represented with a ---(line)


In Ionic compounds:













As you can see here, sodium has 1 valence electron and chlorine has 7.
Sodium and chlorine both want to become happy, and they are attracted to each other. The sodium loses its valence electron and becomes (+)1 charge. Chlorine takes this electron and fills it valence shell, giving it a (-1) charge.  Therefore, this is how the Lewis diagram is shown.



Extra help!

http://www.youtube.com/watch?v=y6QZRBIO0-o
http://www.youtube.com/watch?v=QKoA3fZ29B0